Corrosion of Nickel-based Alloy G30 in the Stratum Water Containing H2S/CO2

The influences of temperature and CO2 pressure on the corrosion of nickel-based alloy G30 in the stratum water containing H2S/CO2 were investigated with the aid Mott-Schottky analysis and scanning electron microscopy（SEM） of electrochemical impedance spectroscopy（EIS）, The results indicate that alloy G30 is in the passive state in the stratum water, which is related to the formation of the passive film on its surface. This passive film can significantly protect the substrate from further corrosion. And the film protection is enhanced with decreasing temperature and CO2 pressure. Auger electron spectrometry（AES） and X-ray photoelectron spectrometry（XPS） results reveal that the passive film shows the double-layer structure, i.e. the inner chromium oxide and the outer iron/nickel spinel oxides or hydroxides with Mo oxides dispersing throughout the inner and outer scale.     

基于无铜点击反应的水凝胶合成

水凝胶是一种交联高分子材料, 在药物传输、传感器技术、组织工程中发挥重要作用。通过高效率和高精确度的点击反应合成水凝胶, 具有快速、模块化以及副反应少等优点, 并且能够得到近乎理想的网络结构。Cu（Ⅰ） 催化的叠氮-炔之间的环加成 （CuAAC） 反应作为点击反应的典型代表, 已广泛应用于水凝胶的制备。但由于该反应在制备水凝胶的过程中使用了Cu（Ⅰ） 催化剂, 导致产品易被金属铜盐污染, 从而使该反应在其制备领域受到限制。基于此, 无铜点击反应,如巯基-烯/炔反应、呋喃/蒽-马来酰亚胺 （MI） 修饰的 Diels-Alder 环加成 （D-A） 反应以及环张力促进的叠氮-炔环加成反应 （SPAAC） 已经被应用到水凝胶的制备以及功能化方面。本文就近年来上述无铜点击反应在水凝胶合成及功能化方面的应用进行综述, 并对其发展趋势进行展望。     

卷云相函数的计算与分析

使用Mie散射理论和FDTD(finite difference time domain)算法,计算了冰晶粒子及其组成的卷云在2.14μm和3.72μm的相函数,讨论了冰晶组分、分布规律、波长及平均有效尺度对其影响.计算结果表明,入射光波长和有效尺度对卷云相函数起主要影响作用,而卷云的冰晶组分和分布规律对其影响不显著.     

Particulate fouling during the pool boiling heat transfer of MWCNT nanofluid

Pool boiling of multi-walled carbon nanotube (MWCNT) nanofluid was conducted to investigate fouling of a copper surface with a diameter of 12?mm. At low heat flux the fouling curve takes the shape of saw tooth with an asymptotic value. When boiling stretches, dispersant, Gum Arabic fails, MWCNT particles deposit on the heating wall completely. Progressively increasing the heat flux, depositing accelerates, superheat and fouling resistance increase drastically.     

Shock-Induced Borehole Waves and Fracture Effects

We perform wave experiments using a vertical shock tube setup. Shock waves are generated by the rupture of a thin membrane. In the test section the incident pressure waves generate borehole-guided waves along water-saturated samples. The tube is equipped with side wall gages and a mobile pressure probe, so that the attenuation and reflection of the wave can be measured. The computation for a single horizontal fracture intersecting a vertical borehole gives a quantitative prediction of reflection and transmission of borehole-guided waves. Three different fracture apertures are used for the calculation. Fracture aperture significantly affects both reflection and transmission coefficients. Large fractures increase reflectivity and decrease transmissivity. In the experiment, we found that both pressures above and below the fracture are influenced by the fracture aperture indeed, thus indicating the potential for fracture detection by borehole waves.     

LEC法生长富磷掺铁InP单晶晶格应变与残留应力研究

运用原位磷注入合成法在高压单晶炉内合成富磷的InP熔体,并利用液封直拉法(LEC)生长出了3英寸富磷掺Fe的InP单晶.运用高分辨率X射线衍射技术、偏振差分透射谱测试技术、光致荧光谱技术对富磷掺Fe的InP晶片进行了结构、应力及发光特性测试.结果表明,晶格的应变导致了PL发光峰峰位的变化,晶格应变与残留应力测试结果相一致,说明材料生长过程中的热应力是导致样品晶格常数分布不均匀的主要因素.     

On the exact solutions to the long–short-wave interaction system

The complete discrimination system for polynomial method is applied to the long-short-wave interaction system to obtain the classifications of single traveling wave solutions. Compared with the solutions given by the （G~/G）-expansion method, we gain some new solutions.     

Implementation of a Free-locking Composite Piezoelectric Shell Element

In this contribution, a free–locking shell element with piezoelectric ceramic layers is presented. The material law and the constitutive equations of the coupled electro–mechanical problem are derived in convective coordinates, so that the presented element accounts for geometrical nonlinearities [2]. To avoid zero–energy mode and locking effects of the thin shell structure, assumed natural strain (ANS) method [1] is implemented. Finally, some numerical examples demonstrate the ability of this element to solve linear and nonlinear problems. (© 2008 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim)     

Theoretical Study on Dissociation Potential Energy Surface of Peroxynitric Acid

The lowest energy structures of peroxynitric acid have been studied with B3LYP/6-311+ G(2d,2p) method. The potential energy surfaces (PES) along the O-N and O-Obonds have been scanned at CCSD(T)/aug-cc-pVDZ level, respectively. The calculated results show that on the O-N PES, the O3-N4 bond length of the loose transition state is 2.82 ? and the corresponding energy barrier is 25.6 kcal/mol, while on the O-O PES, the loose transition state with of O2-O3 bond length of 2.35 ? has the energy barrier of 37.4 kcal/mol. Thus the primary reaction path for peroxynitric acid is the dissociation into HO₂ and NO₂.     

Pt（111）电极上O2与OHad的吸脱附及氧还原反应动力学

研究了Pt（111）电极在0．1mol／LHClO4溶液中O2吸附与OHad脱附及氧还原反应的动力学．研究发现OHad的可逆吸脱附速率很快;在氧还原的动力学或动力学与传质混合控制区,恒电位下氧还原的电流随反应时间缓慢衰减,在转速较大,扫速较慢的情形下正向扫描过程中氧还原的电流总是明显低于逆向扫描的电流;Pt／0．1mol／LHClO4从无O2切换到O2饱和时,其开路电位迅速从0．9V增加到1．0V．结果表明,Pt（111）电极上O2解离生成OHad速率很快,ORR过程中OHad会在表面缓慢积累,氧还原反应的动力学主要由反应 OHad＋H^＋＋e→←H2O的平衡热力学决定．